Solid Silver
What must be the concentration of silver ion in a solution that is in equilibrium with solid silver chloride?
What must be the concentration of silver ion in a solution that is in equilibrium with solid silver chlorideand that is 0.10 M in C^-1?
The concentration of Ag+ (and Cl-) is defined by the solubility product or Ksp for AgCl at 25°C. As long as there is some undissolved AgCl at the bottom of the container - ie the solution is saturated - the actual amount of undissolved AgCl is not taken into account.
The solubility product or Ksp, for AgCl is 1.8 x 10^−10
AgCl dissociates:
AgCl ↔ Ag+ + Cl-
Ksp = ]Ag+] * [Cl-]
But [Ag+] = [Cl-], Therefore:
Ksp = [Ag]²
1.8*10^-10 = [Ag+]²
[Ag+] = √ (1.8*10^-10)
[Ag+] = 1.34*10^-5M That is the molar concentration of the Ag+ion
As an extra, calculate the concentration of AgCl in g/litre
Molar mass AgCl = 143.32 g mol−1
1.34*10^-5 mol = 1.92*10^-3
Solubility of AgCl is 1.92*10^-3 g/litre
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